Product ID:ARKLONE P
MSDS Date:10/02/1987
FSC:6850
NIIN:00-319-0834
MSDS Number: BDWSB

Emergency Phone: 302-575-3000 800-424-9300(CHEMTREC)

Info Phone: 302-275-3000

Cage: 13992

Telephone: 302-886-3000

Cage: 13992

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 99.9%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 43G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:MAY CAUSE SLIGHT
IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:MAY CAUSE GI TRACT
IRRITATION.INHAL:MISTS MAY CAUSE RESPIRATORY IRRITATION AND CARDIAC
SENSITIZATION(IRREGULAR HEARTBEAT).
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:OVEREXPOSURE PROGRESSES FROM IRRITATION TO
WEAKNESS,DEPRESSION,"SPINNING
HEAD",DISORIENTATION,UNCOORDINATION,HEADACHE,DROWSINESS,NAUSEA,LOSS
OF SENSATION,UNCONSCIOUSNESS,POSSIBLE ASPHYXIATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING HEART
AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND
WATER.GET MEDICAL ASSISTANCE FOR REDNESS OR BURNING SKIN.EYES:FLUSH
WITH WATER FOR 15 MINUTES.GET MEDICA ASSISTANCE FOR REDNESS OR
BURNING.INHAL:RE MOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL
RESPIRATION(MOUTH-TO-MOUTH) IF NEEDED.INGEST:DO NOT INDUCE
VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE
1-2 GLASSES OF WATER.

Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVY AND MAY CAUSE
SUFFOCATION.FIRE CONDITIONS MAY EVOLVE TOXIC FUMES.

Spill Release Procedures:ELIMINATE SOURCES OF IGNITION.USE PROPER
RESPIRATORY AND PROTECTIVE EQUIPMENT.VENTILATE AREA.SOAK UP WITH A
NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER
CONTAINER FOR DISPOSAL.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM
HEAT,SPARKS,FLAMES AND INCOMPATIBLE MATERIALS.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS
RESIDUE;DISPOSE OF PROPERLY.VENTILATE LOW LYING AREAS;VAPORS TEND
TO ACCUMULATE THERE AND POSE A SUFFOCATION HAZARD.

Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPORS,DEPENDING ON
THE AIRBORN CONCENTRA TION.
Ventilation:LOCAL VENTILATION AT THE WORKSITE(ESP.LOW LYING
AREAS);MECHANICAL(GENERAL) VENTILATION TO MAINTAIN TLV/PEL.
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NOTE TO PHYSICIAN: DUE TO CARDIAC SENSITIZATION,DO NOT GIVE ADRENALINE(
OR SIMILAR SYMPATHOMIMETIC DRUGS).DO NOT GIVE EPINEPHRINE.DO NOT
ALLOW PATIENT TO EXERCISE VIGOROUSLY WITHIN 24 HOURS OF A POTEN
TIALLY TOXIC EXPOSURE.FREEZE BURNS CAN DEVELOP FROM THE LIQUID FORM
OF THIS MATERIAL.

HCC:T6
Boiling Pt:B.P. Text:117.7F/48C
Decomp Temp:Decomp Text:1300F,704C
Vapor Pres:270
Vapor Density:6.75@117F
Spec Gravity:1.6
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID;COLORLESS;FAINT ETHEREAR ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
MAY REACT VIOLENTLY W SODIUM, POTASSIUM, BARIUM.REACTS WITH FINELY
DIVIDED AL,ZN,MG(ESP. AT HIGH TEMPERATURES).
Stability Condition to Avoid:HIGH HEAT.
Hazardous Decomposition Products:HALOGEN,HALOGEN ACIDS,TRACE AMOUNT OF
CARBONYL HALIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.RCRA CODE IS F002(SPENT HALOGENATED SOLVENTS).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.